Nonlinear kinetics of spinodal decomposition, and dissolution of inhomogeneities formed by spinodal decomposition in polymer blends

NONLINEAR KINETICS OF SPINODAL DECOMPOSITION, AND DISSOLUTION OF INHOMOGENElTIES FORMED BY SPINODAL DECOMPOSITION IN POLYMER BLENDS

Nonlinear kinetics of both spinodal decomposition at early stages, and the dissolution of homogeneities formed during spinodal decomposition,is studied. Variation of the scattering intensity during a complete cycle consisting of a step temperature change from T i in the one-phase. region to T2 in the two-phase region, a period of spinodal decomposition followed by a temperature drop from T2 bac...

Interdiffusion and Spinodal Decomposition in Electrically Conducting Polymer Blends

The impact of phase morphology in electrically conducting polymer composites has become essential for the efficiency of the various functional applications, in which the continuity of the electroactive paths in multicomponent systems is essential. For instance in bulk heterojunction organic solar cells, where the light-induced electron transfer through photon absorption creating excitons (elect...

Isotropic-nematic spinodal decomposition kinetics.

The initial stage of isotropic-nematic spinodal demixing kinetics of suspensions of very long and thin, stiff, repulsive rods is analyzed on the basis of the N-particle Smoluchowski equation. Equations of motion for the reduced probability density function of the position and orientation of a rod are expanded up to second order in spatial gradients and leading order in orientational order param...

Morphological characterization of spinodal decomposition kinetics

The time evolution of the morphology of homogeneous phases during spinodal decomposition is described using a family of morphological measures known as Minkowski functionals. They provide the characteristic length scale L of patterns in a convenient, statistically robust, and computationally inexpensive way. They also allow one to study the scaling behavior of the content, shape, and connectivi...

Spinodal decomposition in microemulsions